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Aqueous synthesis of LiFePO4 with Fractal Granularity.

ABSTRACT: Lithium iron phosphate (LiFePO4) electrodes with fractal granularity are reported. They were made from a starting material prepared in water by a low cost, easy and environmentally friendly hydrothermal method, thus avoiding the use of organic solvents. Our method leads to pure olivine phase, free of the impurities commonly found after other water-based syntheses. The fractal structures consisted of nanoparticles grown into larger micro-sized formations which in turn agglomerate leading to high tap density electrodes, which is beneficial for energy density. These intricate structures could be easily and effectively coated with a thin and uniform carbon layer for increased conductivity, as it is well established for simpler microstructures. Materials and electrodes were studied by means of XRD, SEM, TEM, SAED, XPS, Raman and TGA. Last but not least, lithium transport through fractal LiFePO4 electrodes was investigated based upon fractal theory. These water-made fractal electrodes lead to high-performance lithium cells (even at high rates) tested by CV and galvanostatic charge-discharge, their performance is comparable to state of the art (but less environmentally friendly) electrodes.

SUBMITTER: Caban-Huertas Z

PROVIDER: S-EPMC4891732 | biostudies-literature | 2016 Jun

REPOSITORIES: biostudies-literature

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Aqueous synthesis of LiFePO4 with Fractal Granularity.

Cabán-Huertas Zahilia Z Ayyad Omar O Dubal Deepak P DP Gómez-Romero Pedro P

Scientific reports 20160603

Lithium iron phosphate (LiFePO4) electrodes with fractal granularity are reported. They were made from a starting material prepared in water by a low cost, easy and environmentally friendly hydrothermal method, thus avoiding the use of organic solvents. Our method leads to pure olivine phase, free of the impurities commonly found after other water-based syntheses. The fractal structures consisted of nanoparticles grown into larger micro-sized formations which in turn agglomerate leading to high ...[more]

PMID: 27256504

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Project description:BackgroundMicroservices are an architectural approach of growing use, and the optimal granularity of a microservice directly affects the application's quality attributes and usage of computational resources. Determining microservice granularity is an open research topic.MethodologyWe conducted a systematic literature review to analyze literature that addresses the definition of microservice granularity. We searched in IEEE Xplore, ACM Digital Library and Scopus. The research questions were: Which approaches have been proposed to define microservice granularity and determine the microservices' size? Which metrics are used to evaluate microservice granularity? Which quality attributes are addressed when researching microservice granularity?ResultsWe found 326 papers and selected 29 after applying inclusion and exclusion criteria. The quality attributes most often addressed are runtime properties (e.g., scalability and performance), not development properties (e.g., maintainability). Most proposed metrics were about the product, both static (coupling, cohesion, complexity, source code) and runtime (performance, and usage of computational resources), and a few were about the development team and process. The most used techniques for defining microservices granularity were machine learning (clustering), semantic similarity, genetic programming, and domain engineering. Most papers were concerned with migration from monoliths to microservices; and a few addressed green-field development, but none address improvement of granularity in existing microservice-based systems.ConclusionsMethodologically speaking, microservice granularity research is at a Wild West stage: no standard definition, no clear development-operation trade-offs, and scarce conceptual reuse (e.g., few methods seem applicable or replicable in projects other than their initial proposal). These gaps in granularity research offer clear options to investigate on continuous improvement of the development and operation of microservice-based systems.

Dataset Information

Aqueous synthesis of LiFePO4 with Fractal Granularity.

Publications

Aqueous synthesis of LiFePO4 with Fractal Granularity.

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