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Synthesis of ?-arylated alkylamides via Pd-catalyzed one-pot installation of a directing group and C(sp(3))-H arylation.


ABSTRACT: The synthesis of ?-arylated alkylamides via alkyl C-H bond arylation has been realized by means of direct one-pot reactions of acyl chlorides, aryl iodides and 8-aminoquinoline. Depending on the structure of the starting materials, both single and double ?-arylated alkylamides could be accessed.

SUBMITTER: Liu Y 

PROVIDER: S-EPMC4902048 | biostudies-literature | 2016

REPOSITORIES: biostudies-literature

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Synthesis of β-arylated alkylamides via Pd-catalyzed one-pot installation of a directing group and C(sp(3))-H arylation.

Liu Yunyun Y   Zhang Yi Y   Cao Xiaoji X   Wan Jie-Ping JP  

Beilstein journal of organic chemistry 20160603


The synthesis of β-arylated alkylamides via alkyl C-H bond arylation has been realized by means of direct one-pot reactions of acyl chlorides, aryl iodides and 8-aminoquinoline. Depending on the structure of the starting materials, both single and double β-arylated alkylamides could be accessed. ...[more]

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