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Crystal structure of 3-benzamido-1-(4-nitro-benz-yl)quinolinium tri-fluoro-methane-sulfonate.

ABSTRACT: In the title compound, C23H18N3O3 (+)·CF3SO3 (-), the asymmetric unit contains two crystallographically independent organic cations with similar conformations. Each cation shows a moderate distortion between the planes of the amide groups and the quinolinium rings with dihedral angles of 14.90?(2) and 31.66?(2)°. The quinolinium and phenyl rings are slightly twisted with respect to each other at dihedral angles of 6.99?(4) and 8.54?(4)°. The tri-fluoro-methane-sulfonate anions are linked to the organic cations via N-H?O hydrogen-bonding inter-actions involving the NH amide groups. In the crystal, the organic cations are linked by weak C-H?O(nitro group) inter-actions into supramol-ecular chains propagating along the b-axis direction.

SUBMITTER: Nicolas-Gomez M

PROVIDER: S-EPMC4908536 | biostudies-literature | 2016 May

REPOSITORIES: biostudies-literature

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Crystal structure of 3-benzamido-1-(4-nitro-benz-yl)quinolinium tri-fluoro-methane-sulfonate.

Nicolas-Gomez Mariana M Bazany-Rodríguez Iván J IJ Plata-Vargas Eduardo E Hernández-Ortega Simón S Dorazco-González Alejandro A

Acta crystallographica. Section E, Crystallographic communications 20160429 Pt 5

In the title compound, C23H18N3O3 (+)·CF3SO3 (-), the asymmetric unit contains two crystallographically independent organic cations with similar conformations. Each cation shows a moderate distortion between the planes of the amide groups and the quinolinium rings with dihedral angles of 14.90 (2) and 31.66 (2)°. The quinolinium and phenyl rings are slightly twisted with respect to each other at dihedral angles of 6.99 (4) and 8.54 (4)°. The tri-fluoro-methane-sulfonate anions are linked to the ...[more]

PMID: 27308033

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