Ontology highlight
ABSTRACT:
SUBMITTER: Dhifallah F
PROVIDER: S-EPMC4908550 | biostudies-literature | 2016 Jun
REPOSITORIES: biostudies-literature
Acta crystallographica. Section E, Crystallographic communications 20160520 Pt 6
The crystal structure of the title compound, [Mn(C3H7NO)6][{Mn(C3H7NO)5}2(μ-P2W18O62)]·2C3H7NO, reveals that the Wells-Dawson-type polyanion [P2W18O62](6-), through terminal O atoms from the belts, bridges two Mn(II) octa-hedral complexes. In the complex anion [{Mn(dmf)5}2(μ-P2W18O62)](2-), located around a twofold rotation axis, the Mn(II) ions are coordinated by five O atoms from di-methyl-formamide (dmf) ligands and to a terminal O atom from the [P2W18O62](6-) polyanion. Another Mn(II) ion, l ...[more]