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Synthesis and crystal structure of NaMgFe(MoO4)3.

ABSTRACT: The iron molybdate NaMgFe(MoO4)3 {sodium magnesium iron(III) tris-[molybdate(VI)]} has been synthesized by the flux method. This compound is isostructural with ?-NaFe2(MoO4)3 and crystallizes in the triclinic space group P-1. Its structure is built up from [Mg,Fe]2O10 units of edge-sharing [Mg,Fe]O6 octa-hedra which are linked to each other through the common corners of [MoO4] tetra-hedra. The resulting anionic three-dimensional framework leads to the formation of channels along the [101] direction in which the Na(+) cations are located.

SUBMITTER: Mhiri M

PROVIDER: S-EPMC4908571 | biostudies-literature | 2016 Jun

REPOSITORIES: biostudies-literature

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Synthesis and crystal structure of NaMgFe(MoO4)3.

Mhiri Manel M Badri Abdessalem A Ben Amara Mongi M

Acta crystallographica. Section E, Crystallographic communications 20160527 Pt 6

The iron molybdate NaMgFe(MoO4)3 {sodium magnesium iron(III) tris-[molybdate(VI)]} has been synthesized by the flux method. This compound is isostructural with α-NaFe2(MoO4)3 and crystallizes in the triclinic space group P-1. Its structure is built up from [Mg,Fe]2O10 units of edge-sharing [Mg,Fe]O6 octa-hedra which are linked to each other through the common corners of [MoO4] tetra-hedra. The resulting anionic three-dimensional framework leads to the formation of channels along the [101] direct ...[more]

PMID: 27308061

Dataset Information

Synthesis and crystal structure of NaMgFe(MoO4)3.

Publications

Synthesis and crystal structure of NaMgFe(MoO4)3.

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