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Crystal structure of bis-(2-amino-anilinium) hydrogen phosphate.


ABSTRACT: The asymmetric unit of the title compound, 2C6H9N2 (+)·HPO4 (2-), comprises two 2-amino-anilinium cations and one hydrogen phosphate dianion. In the crystal, the HPO4 (2-) dianions are linked by O-H?O hydrogen bonds into chains along [100]. The inorganic anionic chains and organic cations are linked by N-H?O and N-H?N hydrogen bonds, forming a two-dimensional supra-molecular network extending parallel to (001).

SUBMITTER: Ittyachan R 

PROVIDER: S-EPMC4910340 | biostudies-literature | 2016 Apr

REPOSITORIES: biostudies-literature

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Crystal structure of bis-(2-amino-anilinium) hydrogen phosphate.

Ittyachan Reena R   Ahigna Melesuparambil Sundaram MS   Jagan Rajamony R  

Acta crystallographica. Section E, Crystallographic communications 20160322 Pt 4


The asymmetric unit of the title compound, 2C6H9N2 (+)·HPO4 (2-), comprises two 2-amino-anilinium cations and one hydrogen phosphate dianion. In the crystal, the HPO4 (2-) dianions are linked by O-H⋯O hydrogen bonds into chains along [100]. The inorganic anionic chains and organic cations are linked by N-H⋯O and N-H⋯N hydrogen bonds, forming a two-dimensional supra-molecular network extending parallel to (001). ...[more]

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