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Experimental demonstration of the microscopic origin of circular dichroism in two-dimensional metamaterials.

ABSTRACT: Optical activity and circular dichroism are fascinating physical phenomena originating from the interaction of light with chiral molecules or other nano objects lacking mirror symmetries in three-dimensional (3D) space. While chiral optical properties are weak in most of naturally occurring materials, they can be engineered and significantly enhanced in synthetic optical media known as chiral metamaterials, where the spatial symmetry of their building blocks is broken on a nanoscale. Although originally discovered in 3D structures, circular dichroism can also emerge in a two-dimensional (2D) metasurface. The origin of the resulting circular dichroism is rather subtle, and is related to non-radiative (Ohmic) dissipation of the constituent metamolecules. Because such dissipation occurs on a nanoscale, this effect has never been experimentally probed and visualized. Using a suite of recently developed nanoscale-measurement tools, we establish that the circular dichroism in a nanostructured metasurface occurs due to handedness-dependent Ohmic heating.

SUBMITTER: Khanikaev AB

PROVIDER: S-EPMC4917967 | biostudies-literature | 2016 Jun

REPOSITORIES: biostudies-literature

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Experimental demonstration of the microscopic origin of circular dichroism in two-dimensional metamaterials.

Khanikaev A B AB Arju N N Fan Z Z Purtseladze D D Lu F F Lee J J Sarriugarte P P Schnell M M Hillenbrand R R Belkin M A MA Shvets G G

Nature communications 20160622

Optical activity and circular dichroism are fascinating physical phenomena originating from the interaction of light with chiral molecules or other nano objects lacking mirror symmetries in three-dimensional (3D) space. While chiral optical properties are weak in most of naturally occurring materials, they can be engineered and significantly enhanced in synthetic optical media known as chiral metamaterials, where the spatial symmetry of their building blocks is broken on a nanoscale. Although or ...[more]

PMID: 27329108

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Project description:Metamaterials, rationally designed multiscale composite systems, have attracted extensive interest because of their potential for a broad range of applications due to their unique properties such as negative Poisson's ratio, exceptional mechanical performance, tunable photonic and phononic properties, structural reconfiguration, etc. Though they are dominated by an auxetic structure, the constituents of metamaterials also play an indispensable role in determining their unprecedented properties. In this vein, 2D materials such as graphene, silicene, and phosphorene with superior structural tunability are ideal candidates for constituents of metamaterials. However, the nanostructure-property relationship and composition-property relationship of these 2D material-based metamaterials remain largely unexplored. Mechanical anisotropy inherited from the 2D material constituents, for example, may substantially impact the physical stability and robustness of the corresponding metamaterial systems. Herein, classical molecular dynamics simulations are performed using a generic coarse-grained model to explore the deformation mechanism of these 2D material-based metamaterials with sinusoidally curved ligaments and the effect of mechanical anisotropy on mechanical properties, especially the negative Poisson's ratio. The results indicate that deformation under axial tensile load can be divided into two stages: bending-dominated and stretching-dominated, in which the rotation of junctions in the former stage results in auxetic behavior of the proposed metamaterials. In addition, the auxetic behavior depends heavily on both the amplitude/wavelength ratio of the sinusoidal ligament and the stiffness ratio between axial and transverse directions. The magnitude of negative Poisson's ratio increases from 0 to 0.625, with an associated increase of the amplitude/wavelength ratio from 0 to 0.225, and fluctuates at around 0.625, in good agreement with the literature, with amplitude/wavelength ratios greater than 0.225. More interestingly, the magnitude of negative Poisson's ratio increases from 0.47 to 0.87 with the increase of the stiffness ratio from 0.125 to 8, in good agreement with additional all-atom molecular dynamics simulations for phosphorene and molybdenum disulfide. Overall, these research findings shed light on the deformation mechanism of auxetic metamaterials, providing useful guidelines for designing auxetic 2D lattice structures made of 2D materials that can display a tunable negative Poisson's ratio.

Dataset Information

Experimental demonstration of the microscopic origin of circular dichroism in two-dimensional metamaterials.

Publications

Experimental demonstration of the microscopic origin of circular dichroism in two-dimensional metamaterials.

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