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Single-Crystal X-ray Structures of conductive ?-Stacking Dimers of Tetrakis(alkylthio)benzene Radical Cations.

ABSTRACT: Salts containing radical cations of 1,2,4,5-tetrakis(isopropylthio)benzene (TPB) and 1,2,4,5-tetrakis(ethylthio) benzene (TEB) have been successfully synthesized with . These newly synthesized salts have been characterized by UV-Vis absorption, EPR spectroscopy, conductivity measurement, single crystal X-ray diffraction analysis as well as DFT calculation. This study raises the first crystal structure of conductive ?-stacking radical cation with single phenyl ring and reveals their conductivity has relationship with the stack structure which affected by the substituent.

SUBMITTER: Chen X

PROVIDER: S-EPMC4941407 | biostudies-literature | 2016 Jul

REPOSITORIES: biostudies-literature

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Single-Crystal X-ray Structures of conductive π-Stacking Dimers of Tetrakis(alkylthio)benzene Radical Cations.

Chen Xiaoyu X Gao Feng F Yang Wuqin W

Scientific reports 20160711

Salts containing radical cations of 1,2,4,5-tetrakis(isopropylthio)benzene (TPB) and 1,2,4,5-tetrakis(ethylthio) benzene (TEB) have been successfully synthesized with . These newly synthesized salts have been characterized by UV-Vis absorption, EPR spectroscopy, conductivity measurement, single crystal X-ray diffraction analysis as well as DFT calculation. This study raises the first crystal structure of conductive π-stacking radical cation with single phenyl ring and reveals their conductivity ...[more]

PMID: 27403720

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