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Polar Spinel-Perovskite Interfaces: an atomistic study of Fe3O4(111)/SrTiO3(111) structure and functionality.

ABSTRACT: Atomic resolution scanning transmission electron microscopy and electron energy loss spectroscopy combined with ab initio electronic calculations are used to determine the structure and properties of the Fe3O4(111)/SrTiO3(111) polar interface. The interfacial structure and chemical composition are shown to be atomically sharp and of an octahedral Fe/SrO3 nature. Band alignment across the interface pins the Fermi level in the vicinity of the conduction band of SrTiO3. Density functional theory calculations demonstrate very high spin-polarization of Fe3O4 in the interface vicinity which suggests that this system may be an excellent candidate for spintronic applications.

SUBMITTER: Gilks D

PROVIDER: S-EPMC4944391 | biostudies-literature | 2016 Jul

REPOSITORIES: biostudies-literature

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Polar Spinel-Perovskite Interfaces: an atomistic study of Fe3O4(111)/SrTiO3(111) structure and functionality.

Gilks Daniel D McKenna Keith P KP Nedelkoski Zlatko Z Kuerbanjiang Balati B Matsuzaki Kosuke K Susaki Tomofumi T Lari Leonardo L Kepaptsoglou Demie D Ramasse Quentin Q Tear Steve S Lazarov Vlado K VK

Scientific reports 20160714

Atomic resolution scanning transmission electron microscopy and electron energy loss spectroscopy combined with ab initio electronic calculations are used to determine the structure and properties of the Fe3O4(111)/SrTiO3(111) polar interface. The interfacial structure and chemical composition are shown to be atomically sharp and of an octahedral Fe/SrO3 nature. Band alignment across the interface pins the Fermi level in the vicinity of the conduction band of SrTiO3. Density functional theory ca ...[more]

PMID: 27411576

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