Ontology highlight
ABSTRACT:
SUBMITTER: Khrakovsky DA
PROVIDER: S-EPMC4948301 | biostudies-literature | 2016 May
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20160420 20
The gold-catalyzed enantioselective hydroazidation and hydroamination reactions of allenes are presented herein. ADC gold(I) catalysts derived from BINAM were critical for achieving high levels of enantioselectivity in both transformations. The sense of enantioinduction is reversed for the two different nucleophiles, allowing access to both enantiomers of the corresponding allylic amines using the same catalyst enantiomer. ...[more]