Unknown

Dataset Information

0

A Bifunctional Electrocatalyst for Oxygen Evolution and Oxygen Reduction Reactions in Water.

ABSTRACT: Oxygen reduction and water oxidation are two key processes in fuel cell applications. The oxidation of water to dioxygen is a 4?H+/4?e- process, while oxygen can be fully reduced to water by a 4?e-/4?H+ process or partially reduced by fewer electrons to reactive oxygen species such as H2O2 and O2-. We demonstrate that a novel manganese corrole complex behaves as a bifunctional catalyst for both the electrocatalytic generation of dioxygen as well as the reduction of dioxygen in aqueous media. Furthermore, our combined kinetic, spectroscopic, and electrochemical study of manganese corroles adsorbed on different electrode materials (down to a submolecular level) reveals mechanistic details of the oxygen evolution and reduction processes.

SUBMITTER: Schofberger W 

PROVIDER: S-EPMC4949540 | biostudies-literature | 2016 Feb

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Oxygen reduction and water oxidation are two key processes in fuel cell applications. The oxidation of water to dioxygen is a 4 H<sup>+</sup>/4 e<sup>-</sup> process, while oxygen can be fully reduced to water by a 4 e<sup>-</sup>/4 H<sup>+</sup> process or partially reduced by fewer electrons to reactive oxygen species such as H<sub>2</sub>O<sub>2</sub> and O<sub>2</sub><sup>-</sup>. We demonstrate that a novel manganese corrole complex behaves as a bifunctional catalyst for both the electrocat  ...[more]

Similar Datasets

Unknown A Bifunctional Electrocatalyst for Oxygen Evolution and Oxygen Reduction Reactions in Water.
| S-EPMC4949709 | biostudies-other
Unknown B, N Codoped and Defect-Rich Nanocarbon Material as a Metal-Free Bifunctional Electrocatalyst for Oxygen Reduction and Evolution Reactions.
| S-EPMC6051395 | biostudies-literature
Unknown Advanced Bifunctional Oxygen Reduction and Evolution Electrocatalyst Derived from Surface-Mounted Metal-Organic Frameworks.
| S-EPMC7154533 | biostudies-literature
Unknown Nitrogen-Doped Porous Carbon Derived from Biomass Used as Trifunctional Electrocatalyst toward Oxygen Reduction, Oxygen Evolution and Hydrogen Evolution Reactions.
| S-EPMC7022927 | biostudies-literature
Unknown Nickel nanoparticles supported on a covalent triazine framework as electrocatalyst for oxygen evolution reaction and oxygen reduction reactions.
| S-EPMC7237812 | biostudies-literature
Unknown Thermally reduced mesoporous manganese MOF @reduced graphene oxide nanocomposite as bifunctional electrocatalyst for oxygen reduction and evolution.
| S-EPMC9055589 | biostudies-literature
Unknown CuCo<sub>2</sub>S<sub>4</sub>@B,N-Doped Reduced Graphene Oxide Hybrid as a Bifunctional Electrocatalyst for Oxygen Reduction and Evolution Reactions.
| S-EPMC9202276 | biostudies-literature
Unknown Computational Insight into TM–Nx Embedded Graphene Bifunctional Electrocatalysts for Oxygen Evolution and Reduction Reactions
| S-EPMC9955129 | biostudies-literature
Unknown In Situ Formation of Surface-Induced Oxygen Vacancies in Co9S8/CoO/NC as a Bifunctional Electrocatalyst for Improved Oxygen and Hydrogen Evolution Reactions.
| S-EPMC8471348 | biostudies-literature
Unknown Identification of catalytic sites for oxygen reduction and oxygen evolution in N-doped graphene materials: Development of highly efficient metal-free bifunctional electrocatalyst.
| S-EPMC4846433 | biostudies-literature