Ontology highlight
ABSTRACT:
SUBMITTER: Nagata MK
PROVIDER: S-EPMC4955635 | biostudies-literature | 2016 Aug
REPOSITORIES: biostudies-literature
Nagata Maika K C T MK Brauchle Paul S PS Wang Sen S Briggs Sarah K SK Hong Young Soo YS Laorenza Daniel W DW Lee Andrea G AG Westmoreland T David TD
Polyhedron 20160801
Three new DOTAM (1,4,7,10-tetrakis(acetamido)-1,4,7,10-tetraazacyclododecane) complexes have been synthesized and characterized by X-ray crystallography: [Co(DOTAM)]Cl<sub>2</sub>•3H<sub>2</sub>O, [Ni(DOTAM)]Cl<sub>2</sub>•4H<sub>2</sub>O, and [Cu(DOTAM)](ClO<sub>4</sub>)<sub>2</sub>•H<sub>2</sub>O. Solid state and solution IR spectroscopic features for a series of [M(DOTAM)]<sup>2+</sup> complexes (M=Mn, Co, Cu, Ni, Ca, Zn) correlate with solid state and solution coordination numbers. [Co(DOTAM ...[more]