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Crystal structure of bis-(1-hexyl-N,N-di-methyl-pyridinium) bis-(maleo-nitrile-dithiol-ato)nickelate(II).

ABSTRACT: The asymmetric unit of the title compound, (C13H23N2)2[Ni(C4N2S2)2], consists of a 1-hexyl-N,N-di-methyl-pyridinium cation and one half of a [Ni(mnt)2](2-) dianion (mnt(2-) = maleo-nitrile-dithiol-ate) in which the Ni(2+) cation lies on a crystallographic inversion centre. The square-planar coordination about Ni(2+) comprises four S atoms from two bidentate chelate mnt(2-) ligands [Ni-S = 2.1791?(9) and 2.1810?(8)?Å, and S-Ni-S bite angle = 91.93?(3)°]. The hydro-carbon chains of cations show trans-planar conformations and lie approximately parallel to the long mol-ecular axis of the [Ni(mnt)2](2-) anions, giving stacks along the c axis. The anions and cations form layers lying parallel to the bc plane. Only weak C-H?Ni and C-H?? associations are present in the crystal packing.

SUBMITTER: Yu SS

PROVIDER: S-EPMC4971872 | biostudies-literature | 2016 Aug

REPOSITORIES: biostudies-literature

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Crystal structure of bis-(1-hexyl-N,N-di-methyl-pyridinium) bis-(maleo-nitrile-dithiol-ato)nickelate(II).

Yu Shan-Shan SS Zhang Hui H

Acta crystallographica. Section E, Crystallographic communications 20160726 Pt 8

The asymmetric unit of the title compound, (C13H23N2)2[Ni(C4N2S2)2], consists of a 1-hexyl-N,N-di-methyl-pyridinium cation and one half of a [Ni(mnt)2](2-) dianion (mnt(2-) = maleo-nitrile-dithiol-ate) in which the Ni(2+) cation lies on a crystallographic inversion centre. The square-planar coordination about Ni(2+) comprises four S atoms from two bidentate chelate mnt(2-) ligands [Ni-S = 2.1791 (9) and 2.1810 (8) Å, and S-Ni-S bite angle = 91.93 (3)°]. The hydro-carbon chains of cations show tr ...[more]

PMID: 27536413

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