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Reactivity studies of pincer bis-protic N-heterocyclic carbene complexes of platinum and palladium under basic conditions.


ABSTRACT: Bis-protic N-heterocyclic carbene complexes of platinum and palladium (4) yield dimeric structures 6 when treated with sodium tert-butoxide in CH2Cl2. The use of a more polar solvent (THF) and a strong base (LiN(iPr)2) gave the lithium chloride adducts monobasic complex 7 or analogous dibasic complex 8.

SUBMITTER: Marelius DC 

PROVIDER: S-EPMC4979752 | biostudies-literature | 2016

REPOSITORIES: biostudies-literature

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Reactivity studies of pincer bis-protic N-heterocyclic carbene complexes of platinum and palladium under basic conditions.

Marelius David C DC   Moore Curtis E CE   Rheingold Arnold L AL   Grotjahn Douglas B DB  

Beilstein journal of organic chemistry 20160628


Bis-protic N-heterocyclic carbene complexes of platinum and palladium (4) yield dimeric structures 6 when treated with sodium tert-butoxide in CH2Cl2. The use of a more polar solvent (THF) and a strong base (LiN(iPr)2) gave the lithium chloride adducts monobasic complex 7 or analogous dibasic complex 8. ...[more]

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