Unknown

Dataset Information

0

A Straightforward Electrochemical Approach to Imine- and Amine-bisphenolate Metal Complexes with Facile Control Over Metal Oxidation State.


ABSTRACT: Synthetic methods to prepare organometallic and coordination compounds such as Schiff-base complexes are diverse, with the route chosen being dependent upon many factors such as metal-ligand combination and metal oxidation state. In this work we have shown that electrochemical methodology can be employed to synthesize a variety of metal-salen/salan complexes which comprise diverse metal-ligand combinations and oxidation states. Broad application has been demonstrated through the preparation of 34?complexes under mild and ambient conditions. Unprecedented control over metal oxidation state (M(II/III/IV) where M=Fe, Mn) is presented by simple modification of reaction conditions. Along this route, a general protocol-switch is described which allows access to analytically pure Fe(II/III)-salen complexes. Tuning electrochemical potential, selective metalation of a Mn/Ni alloy is also presented which exclusively delivers Mn(II/IV)-salen complexes in high yield.

SUBMITTER: Chapman MR 

PROVIDER: S-EPMC4981056 | biostudies-literature | 2016 Aug

REPOSITORIES: biostudies-literature

altmetric image

Publications

A Straightforward Electrochemical Approach to Imine- and Amine-bisphenolate Metal Complexes with Facile Control Over Metal Oxidation State.

Chapman Michael R MR   Henkelis Susan E SE   Kapur Nikil N   Nguyen Bao N BN   Willans Charlotte E CE  

ChemistryOpen 20160415 4


Synthetic methods to prepare organometallic and coordination compounds such as Schiff-base complexes are diverse, with the route chosen being dependent upon many factors such as metal-ligand combination and metal oxidation state. In this work we have shown that electrochemical methodology can be employed to synthesize a variety of metal-salen/salan complexes which comprise diverse metal-ligand combinations and oxidation states. Broad application has been demonstrated through the preparation of 3  ...[more]

Similar Datasets

| S-EPMC4394993 | biostudies-literature
| S-EPMC6534343 | biostudies-literature
| S-EPMC10577645 | biostudies-literature
| S-EPMC8306391 | biostudies-literature
| S-EPMC4060467 | biostudies-literature
| S-EPMC3826156 | biostudies-literature
| S-EPMC8146771 | biostudies-literature
| S-EPMC9317992 | biostudies-literature
| S-EPMC4204132 | biostudies-literature
| S-EPMC6641191 | biostudies-literature