Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

A nanostructured surface increases friction exponentially at the solid-gas interface.

ABSTRACT: According to Stokes' law, a moving solid surface experiences viscous drag that is linearly related to its velocity and the viscosity of the medium. The viscous interactions result in dissipation that is known to scale as the square root of the kinematic viscosity times the density of the gas. We observed that when an oscillating surface is modified with nanostructures, the experimentally measured dissipation shows an exponential dependence on kinematic viscosity. The surface nanostructures alter solid-gas interplay greatly, amplifying the dissipation response exponentially for even minute variations in viscosity. Nanostructured resonator thus allows discrimination of otherwise narrow range of gaseous viscosity making dissipation an ideal parameter for analysis of a gaseous media. We attribute the observed exponential enhancement to the stochastic nature of interactions of many coupled nanostructures with the gas media.

SUBMITTER: Phani A

PROVIDER: S-EPMC5011718 | biostudies-literature | 2016 Sep

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

A nanostructured surface increases friction exponentially at the solid-gas interface.

Phani Arindam A Putkaradze Vakhtang V Hawk John E JE Prashanthi Kovur K Thundat Thomas T

Scientific reports 20160906

According to Stokes' law, a moving solid surface experiences viscous drag that is linearly related to its velocity and the viscosity of the medium. The viscous interactions result in dissipation that is known to scale as the square root of the kinematic viscosity times the density of the gas. We observed that when an oscillating surface is modified with nanostructures, the experimentally measured dissipation shows an exponential dependence on kinematic viscosity. The surface nanostructures alter ...[more]

PMID: 27596851

Similar Datasets

Self-Metalation of Porphyrins at the Solid-Gas Interface.

Project description:Self-metalation is a promising route to include a single metal atom in a tetrapyrrolic macrocycle in organic frameworks supported by metal surfaces. The molecule-surface interaction may provide the charge transfer and the geometric distortion of the molecular plane necessary for metal inclusion. However, at a metal surface the presence of an activation barrier can represent an obstacle that cannot be compensated by a higher substrate temperature without affecting the layer integrity. The formation of the intermediate state can be facilitated in some cases by oxygen pre-adsorption at the supporting metal surface, like in the case of 2H-TPP/Pd(100). In such cases, the activation barrier can be overcome by mild annealing, yielding the formation of desorbing products and of the metalated tetrapyrrole. We show here that the self-metalation of 2H-TPP at the Pd(100) surface can be promoted already at room temperature by the presence of an oxygen gas phase at close-to-ambient conditions via an Eley-Rideal mechanism.

| S-EPMC9299001 | biostudies-literature

Accommodative Behavior of Non-porous Molecular crystal at Solid-Gas and Solid-Liquid Interface.

Project description:Molecular crystals demonstrate drastically different behavior in solid and liquid state, mainly due to their difference in structural frameworks. Therefore, designing of unique structured molecular compound which can work at both these interfaces has been a challenge. Here, we present remarkable 'molecular' property by non-porous molecular solid crystal, dinuclear copper complex (C6H5CH(X)NH2)2CuCl2, to reversibly 'adsorb' HCl gas at solid-gas interface as well as 'accommodate' azide anion at solid-liquid interface with crystal to crystal transformation. The latter process is driven by molecular recognition, self-assembly, and anchimeric assistance. The observed transformations are feasible due to breathing of inner and outer coordination sphere around metal center resulting in change in metal polyhedra for 'accommodating' guest molecule. These transformations cause changes in optical, magnetic, and/or ferroelectric property offering diversity in 'sensing' application. With the proposed underlying principles in these exceptional reversible and cyclic transformations, we prepared a series of compounds, can facilitate designing of novel multifunctional molecular materials.

| S-EPMC4585990 | biostudies-literature

Revealing unconventional host-guest complexation at nanostructured interface by surface-enhanced Raman spectroscopy.

Project description:Interfacial host-guest complexation offers a versatile way to functionalize nanomaterials. However, the complicated interfacial environment and trace amounts of components present at the interface make the study of interfacial complexation very difficult. Herein, taking the advantages of near-single-molecule level sensitivity and molecular fingerprint of surface-enhanced Raman spectroscopy (SERS), we reveal that a cooperative effect between cucurbit[7]uril (CB[7]) and methyl viologen (MV2+2I-) in aggregating Au NPs originates from the cooperative adsorption of halide counter anions I-, MV2+, and CB[7] on Au NPs surface. Moreover, similar SERS peak shifts in the control experiments using CB[n]s but with smaller cavity sizes suggested the occurrence of the same guest complexations among CB[5], CB[6], and CB[7] with MV2+. Hence, an unconventional exclusive complexation model is proposed between CB[7] and MV2+ on the surface of Au NPs, distinct from the well-known 1:1 inclusion complexation model in aqueous solutions. In summary, new insights into the fundamental understanding of host-guest interactions at nanostructured interfaces were obtained by SERS, which might be useful for applications related to host-guest chemistry in engineered nanomaterials.

| S-EPMC8055983 | biostudies-literature

Silicon Surface Tethered Polymer as Artificial Solid Electrolyte Interface.

Project description:We have developed a proof of concept electrode design to covalently graft poly(methyl methacrylate) brushes directly to silicon thin film electrodes via surface-initiated atom transfer radical polymerization. This polymer layer acts as a stable artificial solid electrolyte interface that enables surface passivation despite large volume changes during cycling. Thin polymer layers (75?nm) improve average first cycle coulombic efficiency from 62.4% in bare silicon electrodes to 76.3%. Average first cycle reversible capacity was improved from 3157 to 3935 mAh g-1, and average irreversible capacity was reduced from 2011 to 1020 mAh g-1. Electrochemical impedance spectroscopy performed on silicon electrodes showed that resistance from solid electrolyte interface formation increased from 79 to 1508 ? in untreated silicon thin films over 26 cycles, while resistance growth was lower - from 98 to 498 ? - in silicon films functionalized with PMMA brushes. The lower increase suggests enhanced surface passivation and lower electrolyte degradation. This work provides a pathway to develop artificial solid electrolyte interfaces synthesized under controlled reaction conditions.

| S-EPMC6070503 | biostudies-literature

Sea-level rise exponentially increases coastal flood frequency.

Project description:Sea-level rise will radically redefine the coastline of the 21st century. For many coastal regions, projections of global sea-level rise by the year 2100 (e.g., 0.5-2 meters) are comparable in magnitude to today's extreme but short-lived increases in water level due to storms. Thus, the 21st century will see significant changes to coastal flooding regimes (where present-day, extreme-but-rare events become common), which poses a major risk to the safety and sustainability of coastal communities worldwide. So far, estimates of future coastal flooding frequency focus on endpoint scenarios, such as the increase in flooding by 2050 or 2100. Here, we investigate the continuous shift in coastal flooding regimes by quantifying continuous rates of increase in the occurrence of extreme water-level events due to sea-level rise. We find that the odds of exceeding critical water-level thresholds increases exponentially with sea-level rise, meaning that fixed amounts of sea-level rise of only ~1-10 cm in areas with a narrow range of present-day extreme water levels can double the odds of flooding. Combining these growth rates with established sea-level rise projections, we find that the odds of extreme flooding double approximately every 5 years into the future. Further, we find that the present-day 50-year extreme water level (i.e., 2% annual chance of exceedance, based on historical records) will be exceeded annually before 2050 for most (i.e., 70%) of the coastal regions in the United States. Looking even farther into the future, the present-day 50-year extreme water level will be exceeded almost every day during peak tide (i.e., daily mean higher high water) before the end of the 21st century for 90% of the U.S. coast. Our findings underscore the need for immediate planning and adaptation to mitigate the societal impacts of future flooding.

| S-EPMC7162943 | biostudies-literature

Solid friction between soft filaments.

Project description:Any macroscopic deformation of a filamentous bundle is necessarily accompanied by local sliding and/or stretching of the constituent filaments. Yet the nature of the sliding friction between two aligned filaments interacting through multiple contacts remains largely unexplored. Here, by directly measuring the sliding forces between two bundled F-actin filaments, we show that these frictional forces are unexpectedly large, scale logarithmically with sliding velocity as in solid-like friction, and exhibit complex dependence on the filaments' overlap length. We also show that a reduction of the frictional force by orders of magnitude, associated with a transition from solid-like friction to Stokes's drag, can be induced by coating F-actin with polymeric brushes. Furthermore, we observe similar transitions in filamentous microtubules and bacterial flagella. Our findings demonstrate how altering a filament's elasticity, structure and interactions can be used to engineer interfilament friction and thus tune the properties of fibrous composite materials.

| S-EPMC4439330 | biostudies-literature

SKAP binding to microtubules reduces friction at the kinetochore-microtubule interface and increases attachment stability under force.

Project description:The kinetochore links chromosomes to spindle microtubules to drive chromosome segregation at cell division. We recently uncovered that the kinetochore complex Astrin-SKAP, which binds microtubules, reduces rather than increases friction at the mammalian kinetochore-microtubule interface. How it does so is not known. Astrin-SKAP could affect how other kinetochore complexes bind microtubules, reducing their friction along microtubules, or it could itself bind microtubules with similar affinity but lower friction than other attachment factors. Using SKAP mutants unable to bind microtubules, live imaging and laser ablation, we show that SKAP's microtubule binding is essential for sister kinetochore coordination, force dissipation at the interface and attachment responsiveness to force changes. Further, we show that SKAP's microtubule binding is essential to prevent chromosome detachment under both spindle forces and microneedle-generated forces. Together, our findings indicate that SKAP's microtubule binding reduces kinetochore friction and increases attachment responsiveness and stability under force. We propose that having complexes with both high and low sliding friction on microtubules, making a mechanically heterogeneous interface, is key to maintaining robust attachments under force and thus accurate segregation.

| S-EPMC11326240 | biostudies-literature

Multifunctional UV and Gas Sensors Based on Vertically Nanostructured Zinc Oxide: Volume Versus Surface Effect.

Project description:This article reports that it is possible to make multifunctional sensing devices with ZnO infiltrated polymers while the sensing interactions could occur throughout the polymer. As such, we find that infiltrated devices with SU-8 polymer can result in highly sensitive UV sensors. Mesh dielectric core devices were found to make sensitive gas sensors with a better than 5 ppm sensitivity for formaldehyde and NO2. A new type of p-n junction device is further demonstrated that is sensitive to UV illumination, thus making it an enhanced UV sensor. Sensing devices relying on volume interactions, such as light absorption, can significantly benefit from the infiltrated polymer. In contrast, devices that rely on surface interactions, such as gas sensors, do not gain performance in any significant way with or without the infiltrated polymer.

| S-EPMC6539821 | biostudies-literature

Measuring friction at an interface using ultrasonic response.

Project description:Friction between sliding surfaces is a fundamental phenomenon prevalent in many aspects of engineering. There are many sliding contact tribometers that measure friction force in a laboratory environment. However, the transfer of laboratory data to real machine elements is unreliable. Results depend on the specimen configuration, surface condition and environment. In this work, a method has been developed that uses the nonlinear response of a high-power ultrasonic wave to deduce friction coefficient in situ at an interface. When the high-power shear wave strikes a frictional interface, relative slip can occur. It imposes a nonlinear response and causes generation of higher-order odd frequency components in received ultrasonic signals. The amplitude of the harmonics depends on contact stress and local friction coefficient. This nonlinear ultrasonic response has been investigated both numerically and experimentally. A simple one-dimensional model has been used to predict nonlinearity generation. This model has been compared with experiments conducted on aluminium rough surfaces pressed together under increasing loads. Two strategies have been used to estimate the friction coefficient by correlating experimental and numerical third-order nonlinearity. It has proved possible to determine the friction coefficient in situ at the interface; values in the range of 0.22 to 0.61 were measured for different surface configurations.

| S-EPMC7544357 | biostudies-literature

Nanostructured Chemiresistive Gas Sensors for Medical Applications.

Project description:Treating diseases at their earliest stages significantly increases the chance of survival while decreasing the cost of treatment. Therefore, compared to traditional blood testing methods it is the goal of medical diagnostics to deliver a technique that can rapidly predict and if required non-invasively monitor illnesses such as lung cancer, diabetes, melanoma and breast cancer at their very earliest stages, when the chance of recovery is significantly higher. To date human breath nalysis is a promising candidate for fulfilling this need. Here, we highlight the latest key achievements on nanostructured chemiresistive sensors for disease diagnosis by human breath with focus on the multi-scale engineering of both composition and nano-micro scale morphology. We critically assess and compare state-of-the-art devices with the intention to provide direction for the next generation of chemiresistive nanostructured sensors.

| S-EPMC6387115 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data