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An unexpected Lewis acid catalyzed Diels-Alder cycloaddition of aryl allenes and acrylates.

ABSTRACT: An unexpected [4+2] cycloaddition of aryl allenes and simple acrylate derivatives is reported. This process functions well with a variety of allenes and acrylates to generate bi- and tricyclic dihydronaphthalene derivatives through a nonconventional bond disconnection.

SUBMITTER: Conner ML

PROVIDER: S-EPMC5038599 | biostudies-literature | 2016 Jun

REPOSITORIES: biostudies-literature

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An unexpected Lewis acid catalyzed Diels-Alder cycloaddition of aryl allenes and acrylates.

Conner Michael L ML Brown M Kevin MK

Tetrahedron 20160218 26

An unexpected [4+2] cycloaddition of aryl allenes and simple acrylate derivatives is reported. This process functions well with a variety of allenes and acrylates to generate bi- and tricyclic dihydronaphthalene derivatives through a nonconventional bond disconnection. ...[more]

PMID: 27695139

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