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Intermolecular Electronic Coupling of Organic Units for Efficient Persistent Room-Temperature Phosphorescence.

ABSTRACT: Although persistent room-temperature phosphorescence (RTP) emission has been observed for a few pure crystalline organic molecules, there is no consistent mechanism and no universal design strategy for organic persistent RTP (pRTP) materials. A new mechanism for pRTP is presented, based on combining the advantages of different excited-state configurations in coupled intermolecular units, which may be applicable to a wide range of organic molecules. By following this mechanism, we have developed a successful design strategy to obtain bright pRTP by utilizing a heavy halogen atom to further increase the intersystem crossing rate of the coupled units. RTP with a remarkably long lifetime of 0.28?s and a very high quantum efficiency of 5?% was thus obtained under ambient conditions. This strategy represents an important step in the understanding of organic pRTP emission.

SUBMITTER: Yang Z 

PROVIDER: S-EPMC5064736 | biostudies-literature | 2016 Feb

REPOSITORIES: biostudies-literature

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Intermolecular Electronic Coupling of Organic Units for Efficient Persistent Room-Temperature Phosphorescence.

Yang Zhiyong Z   Mao Zhu Z   Zhang Xuepeng X   Ou Depei D   Mu Yingxiao Y   Zhang Yi Y   Zhao Cunyuan C   Liu Siwei S   Chi Zhenguo Z   Xu Jiarui J   Wu Yuan-Chun YC   Lu Po-Yen PY   Lien Alan A   Bryce Martin R MR  

Angewandte Chemie (International ed. in English) 20160106 6

Although persistent room-temperature phosphorescence (RTP) emission has been observed for a few pure crystalline organic molecules, there is no consistent mechanism and no universal design strategy for organic persistent RTP (pRTP) materials. A new mechanism for pRTP is presented, based on combining the advantages of different excited-state configurations in coupled intermolecular units, which may be applicable to a wide range of organic molecules. By following this mechanism, we have developed  ...[more]

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