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Ternary mixtures of ionic liquids for better salt solubility, conductivity and cation transference number improvement.


ABSTRACT: We hereby present the new class of ionic liquid systems in which lithium salt is introduced into the solution as a lithium cation-glyme solvate. This modification leads to the reorganisation of solution structure, which entails release of free mobile lithium cation solvate and hence leads to the significant enhancement of ionic conductivity and lithium cation transference numbers. This new approach in composing electrolytes also enables even three-fold increase of salt concentration in ionic liquids.

SUBMITTER: Karpierz E 

PROVIDER: S-EPMC5073297 | biostudies-literature | 2016 Oct

REPOSITORIES: biostudies-literature

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Ternary mixtures of ionic liquids for better salt solubility, conductivity and cation transference number improvement.

Karpierz E E   Niedzicki L L   Trzeciak T T   Zawadzki M M   Dranka M M   Zachara J J   Żukowska G Z GZ   Bitner-Michalska A A   Wieczorek W W  

Scientific reports 20161021


We hereby present the new class of ionic liquid systems in which lithium salt is introduced into the solution as a lithium cation-glyme solvate. This modification leads to the reorganisation of solution structure, which entails release of free mobile lithium cation solvate and hence leads to the significant enhancement of ionic conductivity and lithium cation transference numbers. This new approach in composing electrolytes also enables even three-fold increase of salt concentration in ionic liq  ...[more]

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