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Rational Synthesis of the Carbonyl(perthiolato)diiron [Fe2(S3CPh2)(CO)6] and Related Complexes.


ABSTRACT: The photochemical reaction of Fe2(S2)(CO)6 and Ph2CS affords the perthiolate Fe2(S3CPh2)(CO)6 (1) in good yield. As confirmed crystallographically, 1 contains a previously elusive perthiolate ligand. The related reaction of Fe2(S2)(CO)5-(PPh3) and Ph2CS gave Fe2(S3CPh2)(CO)5(PPh3). Although Fe3S2(CO)9 and Ph2CS failed to efficiently give Fe2(S2CPh2)(CO)6, this compound could be prepared by desulfurization of 1 using PPh3.

SUBMITTER: Zhao P 

PROVIDER: S-EPMC5089076 | biostudies-literature | 2016 Jun

REPOSITORIES: biostudies-literature

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Rational Synthesis of the Carbonyl(perthiolato)diiron [Fe<sub>2</sub>(S<sub>3</sub>CPh<sub>2</sub>)(CO)<sub>6</sub>] and Related Complexes.

Zhao Peihua P   Gray Danielle L DL   Rauchfuss Thomas B TB  

European journal of inorganic chemistry 20160519 17


The photochemical reaction of Fe<sub>2</sub>(S<sub>2</sub>)(CO)<sub>6</sub> and Ph<sub>2</sub>CS affords the perthiolate Fe<sub>2</sub>(S<sub>3</sub>CPh<sub>2</sub>)(CO)<sub>6</sub> (<b>1</b>) in good yield. As confirmed crystallographically, <b>1</b> contains a previously elusive perthiolate ligand. The related reaction of Fe<sub>2</sub>(S<sub>2</sub>)(CO)<sub>5</sub>-(PPh<sub>3</sub>) and Ph<sub>2</sub>CS gave Fe<sub>2</sub>(S<sub>3</sub>CPh<sub>2</sub>)(CO)<sub>5</sub>(PPh<sub>3</sub>). Altho  ...[more]

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