Rational Synthesis of the Carbonyl(perthiolato)diiron [Fe2(S3CPh2)(CO)6] and Related Complexes.
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SUBMITTER: Zhao P
PROVIDER: S-EPMC5089076 | biostudies-literature | 2016 Jun
REPOSITORIES: biostudies-literature
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Rational Synthesis of the Carbonyl(perthiolato)diiron [Fe<sub>2</sub>(S<sub>3</sub>CPh<sub>2</sub>)(CO)<sub>6</sub>] and Related Complexes.
Zhao Peihua P Gray Danielle L DL Rauchfuss Thomas B TB
European journal of inorganic chemistry 20160519 17
The photochemical reaction of Fe<sub>2</sub>(S<sub>2</sub>)(CO)<sub>6</sub> and Ph<sub>2</sub>CS affords the perthiolate Fe<sub>2</sub>(S<sub>3</sub>CPh<sub>2</sub>)(CO)<sub>6</sub> (<b>1</b>) in good yield. As confirmed crystallographically, <b>1</b> contains a previously elusive perthiolate ligand. The related reaction of Fe<sub>2</sub>(S<sub>2</sub>)(CO)<sub>5</sub>-(PPh<sub>3</sub>) and Ph<sub>2</sub>CS gave Fe<sub>2</sub>(S<sub>3</sub>CPh<sub>2</sub>)(CO)<sub>5</sub>(PPh<sub>3</sub>). Altho ...[more]
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