Ontology highlight
ABSTRACT:
SUBMITTER: Feng J
PROVIDER: S-EPMC5096378 | biostudies-literature | 2016 Sep
REPOSITORIES: biostudies-literature
Journal of the American Chemical Society 20160915 38
Total syntheses of oridamycin A, triptoquinones B and C, and isoiresin are accomplished from a common intermediate prepared via iridium-catalyzed alcohol C-H tert-(hydroxy)prenylation - a byproduct-free process that forms an all-carbon quaternary stereocenter with excellent control of diastereo- and enantioselectivity. ...[more]