Unknown

Dataset Information

0

Reactions of HDDA-Derived Benzynes with Perylenes: Rapid Construction of Polycyclic Aromatic Compounds.

ABSTRACT: Benzynes produced by the thermal cycloisomerization of tetrayne substrates [i.e., by the hexadehydro-Diels-Alder (HDDA) reaction] react with perylenes to produce novel naphthoperylene derivatives. Cyclic voltammetry and absorption and emission properties of these compounds are described. DFT studies shed additional light on the dearomatization that accompanies the reaction as well as some of the spectroscopic behavior.

SUBMITTER: Xu F 

PROVIDER: S-EPMC5107110 | biostudies-literature | 2016 Nov

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Reactions of HDDA-Derived Benzynes with Perylenes: Rapid Construction of Polycyclic Aromatic Compounds.

Xu Feng F   Xiao Xiao X   Hoye Thomas R TR  

Organic letters 20161021 21

Benzynes produced by the thermal cycloisomerization of tetrayne substrates [i.e., by the hexadehydro-Diels-Alder (HDDA) reaction] react with perylenes to produce novel naphthoperylene derivatives. Cyclic voltammetry and absorption and emission properties of these compounds are described. DFT studies shed additional light on the dearomatization that accompanies the reaction as well as some of the spectroscopic behavior. ...[more]

Similar Datasets

Unknown Reactions of HDDA-Derived Benzynes with Sulfides: Mechanism, Modes, and Three-Component Reactions.
| S-EPMC5136460 | biostudies-literature
Unknown Reactions of Hexadehydro-Diels-Alder (HDDA)-Derived Benzynes with Thioamides: Synthesis of Dihydrobenzothiazino-Heterocyclics.
| S-EPMC5629071 | biostudies-literature
Unknown Reactions of HDDA Benzynes with <i>C,N</i>-Diarylimines (ArCH=NAr').
| S-EPMC7990319 | biostudies-literature
Unknown Ring closing and opening reactions leading to aza-polycyclic aromatic compounds.
| S-EPMC3797622 | biostudies-literature
Unknown The Phenol-Ene Reaction: Biaryl Synthesis via Trapping Reactions between HDDA-Generated Benzynes and Phenolics.
| S-EPMC5107112 | biostudies-literature
Unknown CYCLOADDITION REACTIONS OF AZIDE, FURAN, AND PYRROLE UNITS WITH BENZYNES GENERATED BY THE HEXADEHYDRO-DIELS-ALDER (HDDA) REACTION.
| S-EPMC4045115 | biostudies-literature
Unknown Consecutive HDDA and TDDA reactions of silicon-tethered tetraynes for the synthesis of dibenzosilole-fused polycyclic compounds and their unique reactivity.
| S-EPMC6625486 | biostudies-other
Unknown Annulative ?-extension of indoles and pyrroles with diiodobiaryls by Pd catalysis: rapid synthesis of nitrogen-containing polycyclic aromatic compounds.
| S-EPMC6180308 | biostudies-literature
Unknown Rapid, Parallel Identification of Catabolism Pathways of Lignin-Derived Aromatic Compounds in Novosphingobium aromaticivorans.
| S-EPMC6210112 | biostudies-literature
Genomics Polycyclic aromatic hydrocarbons degraders
| PRJNA590550 | ENA