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Specific derivatization of lysozyme in aqueous solution with Re(CO)3(H2O)3(+).

ABSTRACT: The reaction of Re(CO)(3)(H(2)O)(3)(+) with hen egg lysozyme in aqueous solution results in a single covalent adduct; single crystal X-ray diffraction shows that the rhenium tricarbonyl cation binds to His15 in two significantly populated rotamer conformations.

SUBMITTER: Binkley SL 

PROVIDER: S-EPMC5110033 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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Specific derivatization of lysozyme in aqueous solution with Re(CO)3(H2O)3(+).

Binkley Sarah L SL   Ziegler Christopher J CJ   Herrick Richard S RS   Rowlett Roger S RS  

Chemical communications (Cambridge, England) 20100109 8

The reaction of Re(CO)(3)(H(2)O)(3)(+) with hen egg lysozyme in aqueous solution results in a single covalent adduct; single crystal X-ray diffraction shows that the rhenium tricarbonyl cation binds to His15 in two significantly populated rotamer conformations. ...[more]

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