Ontology highlight
ABSTRACT:
SUBMITTER: Barendt TA
PROVIDER: S-EPMC5113793 | biostudies-literature | 2016 Sep
REPOSITORIES: biostudies-literature
Angewandte Chemie (International ed. in English) 20160720 37
The synthesis of the first halogen bonding [3]rotaxane host system containing a bis-iodo triazolium-bis-naphthalene diimide four station axle component is reported. Proton NMR anion binding titration experiments revealed the halogen bonding rotaxane is selective for nitrate over the more basic acetate, hydrogen carbonate and dihydrogen phosphate oxoanions and chloride, and exhibits enhanced recognition of anions relative to a hydrogen bonding analogue. This elaborate interlocked anion receptor f ...[more]