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A Highly Energetic N-Rich Zeolite-Like Metal-Organic Framework with Excellent Air Stability and Insensitivity.

ABSTRACT: A stable N-rich aromatic ligand is employed to prepare energetic zeolite-like metal-organic frameworks. IFMC-1 shows excellent air stability, and the lowest sensitivity toward impact, friction, and electrostatic discharge and the highest predicted heat of detonation among the reported coordination polymers, and even commercial materials (such as trinitrotoluene (TNT)).

SUBMITTER: Qin JS

PROVIDER: S-EPMC5115308 | biostudies-literature | 2015 Dec

REPOSITORIES: biostudies-literature

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A Highly Energetic N-Rich Zeolite-Like Metal-Organic Framework with Excellent Air Stability and Insensitivity.

Qin Jun-Sheng JS Zhang Ji-Chuan JC Zhang Min M Du Dong-Ying DY Li Jing J Su Zhong-Min ZM Wang Yuan-Yuan YY Pang Si-Ping SP Li Sheng-Hua SH Lan Ya-Qian YQ

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20150807 12

<b>A stable N-rich aromatic ligand</b> is employed to prepare energetic zeolite-like metal-organic frameworks. <b>IFMC-1</b> shows excellent air stability, and the lowest sensitivity toward impact, friction, and electrostatic discharge and the highest predicted heat of detonation among the reported coordination polymers, and even commercial materials (such as trinitrotoluene (TNT)). ...[more]

PMID: 27980922

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