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Switching Dielectric Constant Near Room Temperature in a Molecular Crystal.

ABSTRACT: The organic salt bis(2-chloroethyl)amine hydrochloride shows a sharp switching of its dielectric constant at 320 K. The switching property originates from the dynamic changes of the (2-chloroethyl)ammonium cation between frozen and motional states, corresponding to a structural phase transition.

SUBMITTER: Shao XD 

PROVIDER: S-EPMC5115362 | biostudies-literature | 2015 May

REPOSITORIES: biostudies-literature

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Switching Dielectric Constant Near Room Temperature in a Molecular Crystal.

Shao Xiu-Dan XD   Zhang Xi X   Shi Chao C   Yao Ye-Feng YF   Zhang Wen W  

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20150414 5

<b>The organic salt bis(2-chloroethyl)amine hydrochloride</b> shows a sharp switching of its dielectric constant at 320 K. The switching property originates from the dynamic changes of the (2-chloroethyl)ammonium cation between frozen and motional states, corresponding to a structural phase transition. ...[more]

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