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Air-Stable Copper-Based P2-Na7/9Cu2/9Fe1/9Mn2/3O2 as a New Positive Electrode Material for Sodium-Ion Batteries.


ABSTRACT: An air-stable copper-based P2-Na7/9Cu2/9Fe1/9Mn2/3O2 is designed and synthesized by a simple solid-state method and investigated as a positive electrode material for sodium-ion batteries. The attractive long cycling stability is demonstrated by the capacity retention of 85% after 150 cycles at 1 C rate without phase transformation. The reversible Cu2+/Cu3+ redox couple in P2 phase oxides is proved for the first time.

SUBMITTER: Li Y 

PROVIDER: S-EPMC5115408 | biostudies-literature | 2015 Jun

REPOSITORIES: biostudies-literature

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Air-Stable Copper-Based P2-Na<sub>7/9</sub>Cu<sub>2/9</sub>Fe<sub>1/9</sub>Mn<sub>2/3</sub>O<sub>2</sub> as a New Positive Electrode Material for Sodium-Ion Batteries.

Li Yunming Y   Yang Zhenzhong Z   Xu Shuyin S   Mu Linqin L   Gu Lin L   Hu Yong-Sheng YS   Li Hong H   Chen Liquan L  

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20150504 6


<b>An air-stable copper-based P2-Na<sub>7/9</sub>Cu<sub>2/9</sub>Fe<sub>1/9</sub>Mn<sub>2/3</sub>O<sub>2</sub></b> is designed and synthesized by a simple solid-state method and investigated as a positive electrode material for sodium-ion batteries. The attractive long cycling stability is demonstrated by the capacity retention of 85% after 150 cycles at 1 C rate without phase transformation. The reversible Cu<sup>2+</sup>/Cu<sup>3+</sup> redox couple in P2 phase oxides is proved for the first t  ...[more]

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