An unprecedented binuclear cadmium di-thio-carbamate adduct: bis-[μ₂-N-(2-hydroxy-eth-yl)-N-iso-propyl-carbamodi-thio-ato-κ³S:S,S']bis-{[N-(2-hydroxy-eth-yl)-N-iso-propyl-carbamodi-thio-ato-κ²S,S'](3-{(1E)-[(E)-2-(pyridin-3-yl-methyl-idene)hydrazin-1-yl-idene]meth-yl}pyridine-κN)cadmium]} dihydrate.

ABSTRACT: The asymmetric unit in the title binuclear compound, [Cd(C₆H₁₂NOS₂)₂(C₁₂H₁₀N₄)]₂·2H₂O, comprises a Cd^II atom, two di-thio-carbamate (dtc) anions, a monodentate 3-pyridine-aldazine ligand and a lattice water mol-ecule. The binuclear mol-ecule is constructed by the application of inversion symmetry. One dtc ligand simultaneously chelates one cadmium atom and bridges the centrosymmetric mate, while the other dtc ligand is chelating only. This leads to a centrosymmetric [Cd(dtc)₂]₂ core to which are appended two 3-pyridine-aldazine ligands. The resulting NS₅ donor set is based on an octa-hedron. The three-dimensional mol-ecular packing is sustained by h

SUBMITTER: Arman HD 

PROVIDER: S-EPMC5120695 | biostudies-literature | 2016 Sep

REPOSITORIES: biostudies-literature