Ontology highlight
ABSTRACT:
SUBMITTER: Armstrong KC
PROVIDER: S-EPMC5127600 | biostudies-literature | 2016 Nov
REPOSITORIES: biostudies-literature
Armstrong Keith C KC Hohloch Stephan S Lohrey Trevor D TD Zarkesh Ryan A RA Arnold John J Anstey Mitchell R MR
Dalton transactions (Cambridge, England : 2003) 20161101 46
The first synthesis of anion capped cerium corrole complexes is reported. Unusual clustering of the lanthanide corrole units has been found and the degree of aggregation can be controlled by the choice of the capping ligand. A polymeric structure 1a, with the general formula [Cor-Ce(THF)-Cp-Na]<sub>n</sub> (Cor = 5,15-bis(2,4,6-trimethylphenyl)-10-(4 methoxyphenyl)-corrole, THF = tetrahydrofuran), is formed using sodium cyclopentadienide (NaCp) and a dimeric structure 2a, with the general formul ...[more]