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Syntheses, Structures, and Complexation Studies of Tris(organostannyl)methane Derivatives.


ABSTRACT: The syntheses of tris(organostannyl)methanes HC(SnX n Ph(3-n))3 (1, n=0; 2, n=1, X=I; 3, n=1, X =F; 4, n=1, X=Cl; 5, n=1, X=OAc; 6, n=2, X=I; 7, n=2, X=Cl) and the organostannate complexes Et4N[HC(SnIPh2)3?F]?(8), Ph4P[HC(SnClPh2)3?Cl]?(9), and [Ph4P]2[HC(SnCl2Ph)3?2?Cl]?(10) are reported. The compounds were characterized by 1H, 13C, 19F, and 119Sn NMR spectroscopy, IR spectroscopy, electrospray mass spectrometry, and (with the exception of 3) single-crystal X-ray diffraction analysis. From the reaction between 2 and AgClO4 resulted the unprecedented hexanuclear organotin oxocluster [HC{Sn(ClO4)2Ph2}2Sn(OH)2Ph]2?(11), the molecular structure of which was elucidated by using X-ray crystallography.

SUBMITTER: Wendji AS 

PROVIDER: S-EPMC5167309 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature

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Syntheses, Structures, and Complexation Studies of Tris(organostannyl)methane Derivatives.

Wendji Anicet Siakam AS   Lutter Michael M   Stratmann Lukas M LM   Jurkschat Klaus K  

ChemistryOpen 20161025 6


The syntheses of tris(organostannyl)methanes HC(SnX <sub><i>n</i></sub> Ph<sub>(3-<i>n</i>)</sub>)<sub>3</sub> (<b>1</b>, <i>n</i>=0; <b>2</b>, <i>n</i>=1, X=I; <b>3</b>, <i>n</i>=1, X =F; <b>4</b>, <i>n</i>=1, X=Cl; <b>5</b>, <i>n</i>=1, X=OAc; <b>6</b>, <i>n</i>=2, X=I; <b>7</b>, <i>n</i>=2, X=Cl) and the organostannate complexes Et<sub>4</sub>N[HC(SnIPh<sub>2</sub>)<sub>3</sub>⋅F] (<b>8</b>), Ph<sub>4</sub>P[HC(SnClPh<sub>2</sub>)<sub>3</sub>⋅Cl] (<b>9</b>), and [Ph<sub>4</sub>P]<sub>2</sub>[  ...[more]

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