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Regioselective Hydrohydroxyalkylation of Styrene with Primary Alcohols or Aldehydes via Ruthenium-Catalyzed C-C Bond Forming Transfer Hydrogenation.

ABSTRACT: Transfer hydrogenative coupling of styrene with primary alcohols using the precatalyst HClRu(CO)(PCy3 )2 modified by AgOTf or HBF4 delivers branched or linear adducts from benzylic or aliphatic alcohols, respectively. Related 2-propanol mediated reductive couplings also are described.

SUBMITTER: Xiao H 

PROVIDER: S-EPMC5189692 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature

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Regioselective Hydrohydroxyalkylation of Styrene with Primary Alcohols or Aldehydes via Ruthenium-Catalyzed C-C Bond Forming Transfer Hydrogenation.

Xiao Hongde H   Wang Gang G   Krische Michael J MJ  

Angewandte Chemie (International ed. in English) 20161202 52

Transfer hydrogenative coupling of styrene with primary alcohols using the precatalyst HClRu(CO)(PCy<sub>3</sub> )<sub>2</sub> modified by AgOTf or HBF<sub>4</sub> delivers branched or linear adducts from benzylic or aliphatic alcohols, respectively. Related 2-propanol mediated reductive couplings also are described. ...[more]

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