Unknown

Dataset Information

0

Regioselective Hydrohydroxyalkylation of Styrene with Primary Alcohols or Aldehydes via Ruthenium-Catalyzed C-C Bond Forming Transfer Hydrogenation.


ABSTRACT: Transfer hydrogenative coupling of styrene with primary alcohols using the precatalyst HClRu(CO)(PCy3 )2 modified by AgOTf or HBF4 delivers branched or linear adducts from benzylic or aliphatic alcohols, respectively. Related 2-propanol mediated reductive couplings also are described.

SUBMITTER: Xiao H 

PROVIDER: S-EPMC5189692 | biostudies-literature | 2016 Dec

REPOSITORIES: biostudies-literature

altmetric image

Publications

Regioselective Hydrohydroxyalkylation of Styrene with Primary Alcohols or Aldehydes via Ruthenium-Catalyzed C-C Bond Forming Transfer Hydrogenation.

Xiao Hongde H   Wang Gang G   Krische Michael J MJ  

Angewandte Chemie (International ed. in English) 20161202 52


Transfer hydrogenative coupling of styrene with primary alcohols using the precatalyst HClRu(CO)(PCy<sub>3</sub> )<sub>2</sub> modified by AgOTf or HBF<sub>4</sub> delivers branched or linear adducts from benzylic or aliphatic alcohols, respectively. Related 2-propanol mediated reductive couplings also are described. ...[more]

Similar Datasets

| S-EPMC3165010 | biostudies-literature
| S-EPMC5950558 | biostudies-literature
| S-EPMC3800700 | biostudies-literature
| S-EPMC2845390 | biostudies-literature
| S-EPMC8694324 | biostudies-literature
| S-EPMC4385519 | biostudies-literature
| S-EPMC3855325 | biostudies-literature
| S-EPMC2897757 | biostudies-literature
| S-EPMC3397400 | biostudies-literature
| S-EPMC4470559 | biostudies-literature