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One-Pot Click Access to a Cyclodextrin Dimer-Based Novel Aggregation Induced Emission Sensor and Monomer-Based Chiral Stationary Phase.

ABSTRACT: A 'two birds, one stone' strategy was developed via a one-pot click reaction to simultaneously prepare a novel cyclodextrin (CD) dimer based aggregation induced emission (AIE) sensor (AIE-DCD) and a monomer based chiral stationary phase (CSP-MCD) for chiral high performance liquid chromatography (CHPLC). AIE-DCD was found to afford satisfactory AIE response for specific detection of Zn2+ with a detection limit of 50 nM. CSP-MCD exhibits excellent enantioseparation ability toward dansyl amino acids, where the resolution of dansyl amino leucine reaches 5.43.

SUBMITTER: Li X

PROVIDER: S-EPMC5190966 | biostudies-literature | 2016 Nov

REPOSITORIES: biostudies-literature

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One-Pot Click Access to a Cyclodextrin Dimer-Based Novel Aggregation Induced Emission Sensor and Monomer-Based Chiral Stationary Phase.

Li Xiaoli X Zhao Rui R Tang Xiaoying X Shi Yanyan Y Li Chunyi C Wang Yong Y

Sensors (Basel, Switzerland) 20161124 12

A 'two birds, one stone' strategy was developed via a one-pot click reaction to simultaneously prepare a novel cyclodextrin (CD) dimer based aggregation induced emission (AIE) sensor (AIE-DCD) and a monomer based chiral stationary phase (CSP-MCD) for chiral high performance liquid chromatography (CHPLC). AIE-DCD was found to afford satisfactory AIE response for specific detection of Zn<sup>2+</sup> with a detection limit of 50 nM. CSP-MCD exhibits excellent enantioseparation ability toward dansy ...[more]

PMID: 27886123

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