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Crystal structure of chlorido-[1-(4-nitro-phen-yl)thio-urea-?S]bis-(tri-phenyl-phosphane-?P)copper(I).

ABSTRACT: The mononuclear mixed-ligand title complex, [CuCl(C₇H₇N₃O₂S)(C₁₈H₁₅P)₂], displays a distorted tetra-hedral coordination sphere around the Cu^I atom, with two P atoms from two tri-phenyl-phosphane mol-ecules, one terminal S atom from a 1-(4-nitro-phen-yl)thio-urea mol-ecule and a chloride ion as ligands. An intra-molecular N-H?Cl hydrogen bond stabilizes the mol-ecular conformation [graph-set motif R₂²(6)]. In the crystal, further N-H?Cl hydrogen bonds connect individual mol-ecules into zigzag chains parallel to [001]. The chains are linked by weak C-H?O hydrogen-bonding inter-actions into a three-dimensional network.

SUBMITTER: Nimthong-Roldan A

PROVIDER: S-EPMC5209768 | biostudies-literature | 2017 Jan

REPOSITORIES: biostudies-literature

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Crystal structure of chlorido-[1-(4-nitro-phen-yl)thio-urea-κS]bis-(tri-phenyl-phosphane-κP)copper(I).

Nimthong-Roldán Arunpatcha A Promsuwhan Nichakan N Puetpaiboon Walailak W Wattanakanjana Yupa Y

Acta crystallographica. Section E, Crystallographic communications 20170101 Pt 1

The mononuclear mixed-ligand title complex, [CuCl(C7H7N3O2S)(C18H15P)2], displays a distorted tetra-hedral coordination sphere around the CuI atom, with two P atoms from two tri-phenyl-phosphane mol-ecules, one terminal S atom from a 1-(4-nitro-phen-yl)thio-urea mol-ecule and a chloride ion as ligands. An intra-molecular N-H⋯Cl hydrogen bond stabilizes the mol-ecular conformation [graph-set motif R<sub ...[more]

PMID: 28083132

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