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Supramolecular frameworks based on [60]fullerene hexakisadducts.


ABSTRACT: [60]Fullerene hexakisadducts possessing 12 carboxylic acid side chains form crystalline hydrogen-bonding frameworks in the solid state. Depending on the length of the linker between the reactive sites and the malonate units, the distance of the [60]fullerene nodes and thereby the spacing of the frameworks can be controlled and for the most elongated derivative, continuous channels are obtained within the structure. Stability, structural integrity and porosity of the material were investigated by powder X-ray diffraction, thermogravimetry and sorption measurements.

SUBMITTER: Kraft A 

PROVIDER: S-EPMC5238557 | biostudies-literature | 2017

REPOSITORIES: biostudies-literature

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Supramolecular frameworks based on [60]fullerene hexakisadducts.

Kraft Andreas A   Stangl Johannes J   Krause Ana-Maria AM   Müller-Buschbaum Klaus K   Beuerle Florian F  

Beilstein journal of organic chemistry 20170102


[60]Fullerene hexakisadducts possessing 12 carboxylic acid side chains form crystalline hydrogen-bonding frameworks in the solid state. Depending on the length of the linker between the reactive sites and the malonate units, the distance of the [60]fullerene nodes and thereby the spacing of the frameworks can be controlled and for the most elongated derivative, continuous channels are obtained within the structure. Stability, structural integrity and porosity of the material were investigated by  ...[more]

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