Ontology highlight
ABSTRACT:
SUBMITTER: Chalkov NO
PROVIDER: S-EPMC5238573 | biostudies-literature | 2016
REPOSITORIES: biostudies-literature
Beilstein journal of organic chemistry 20161117
The chemical oxidation and reduction processes of deprotonated, direduced <i>o</i>-quinone-exTTF-<i>o</i>-quinone in protic solvents were studied by EPR spectroscopy. The formation of relatively stable paramagnetic protonated redox forms of the parent triad was very surprising. The character of spin-density distribution in the semiquinone-quinone and semiquinone-catechol redox forms indicates that the <i>p</i>-phenylene-extended tetrathiafulvalene connector provides a quite effective electronic ...[more]