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Relaxation dynamics in the strong chalcogenide glass-former of Ge₂₂Se₇₈.

ABSTRACT: The enthalpy relaxation is performed in the glassy Ge₂₂Se₇₈ to understand the dynamic behaviors. The structure of the glass is examined by X-ray diffraction and Raman spectra. The dynamic parameters such as the fragility, stretching exponent and non-linear factor are determined. A low fragility of m = 27 is exhibited for the chalcogenide, however, the stretching exponent is found not to have a larger value. The enthalpy relaxation spectra are constructed for various glass formers, and a relationship between the fragility and the symmetry of the spectra is demonstrated. The dynamic results are used to evaluate the structure of the Ge₂₂Se₇₈ glass.

SUBMITTER: Li P

PROVIDER: S-EPMC5240093 | biostudies-literature |

REPOSITORIES: biostudies-literature

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