Indefinitely stable iron(IV) cage complexes formed in water by air oxidation.
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ABSTRACT:
SUBMITTER: Tomyn S
PROVIDER: S-EPMC5253674 | biostudies-literature | 2017 Jan
REPOSITORIES: biostudies-literature
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Indefinitely stable iron(IV) cage complexes formed in water by air oxidation.
Tomyn Stefania S Shylin Sergii I SI Bykov Dmytro D Ksenofontov Vadim V Gumienna-Kontecka Elzbieta E Bon Volodymyr V Fritsky Igor O IO
Nature communications 20170119
In nature, iron, the fourth most abundant element of the Earth's crust, occurs in its stable forms either as the native metal or in its compounds in the +2 or +3 (low-valent) oxidation states. High-valent iron (+4, +5, +6) compounds are not formed spontaneously at ambient conditions, and the ones obtained synthetically appear to be unstable in polar organic solvents, especially aqueous solutions, and this is what limits their studies and use. Here we describe unprecedented iron(IV) hexahydrazide ...[more]
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