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Di-n-butyl-bis-[N-(2-meth-oxy-eth-yl)-N-methyl-dithio-carbamato-?2S,S']tin(IV): crystal structure and Hirshfeld surface analysis.

ABSTRACT: The complete mol-ecule of the title compound, [Sn(C4H9)2(C5H10NOS2)2], is generated by a crystallographic mirror plane, with the SnIV atom and the two inner methyl-ene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl groups, which deviate from mirror symmetry. The di-thio-carbamate ligand coordinates to the metal atom in an asymmetric mode with the resulting C2S4 donor set defining a skew trapezoidal bipyramidal geometry; the n-butyl groups are disposed to lie over the longer Sn-S bonds. Supra-molecular chains aligned along the a-axis direction and sustained by methyl-ene-C-H?S(weakly coordinating) inter-actions feature in the mol-ecular packing. A Hirshfeld surface analysis reveals the dominance of H?H contacts in the crystal.

SUBMITTER: Mohamad R 

PROVIDER: S-EPMC5290578 | biostudies-literature | 2017 Feb

REPOSITORIES: biostudies-literature

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Di-<i>n</i>-butyl-bis-[<i>N</i>-(2-meth-oxy-eth-yl)-<i>N</i>-methyl-dithio-carbamato-κ<sup>2</sup><i>S</i>,<i>S</i>']tin(IV): crystal structure and Hirshfeld surface analysis.

Mohamad Rapidah R   Awang Normah N   Kamaludin Nurul F NF   Jotani Mukesh M MM   Tiekink Edward R T ER  

Acta crystallographica. Section E, Crystallographic communications 20170127 Pt 2

The complete mol-ecule of the title compound, [Sn(C<sub>4</sub>H<sub>9</sub>)<sub>2</sub>(C<sub>5</sub>H<sub>10</sub>NOS<sub>2</sub>)<sub>2</sub>], is generated by a crystallographic mirror plane, with the Sn<sup>IV</sup> atom and the two inner methyl-ene C atoms of the butyl ligands lying on the mirror plane; statistical disorder is noted in the two terminal ethyl groups, which deviate from mirror symmetry. The di-thio-carbamate ligand coordinates to the metal atom in an asymmetric mode with th  ...[more]

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