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Re-Determination of the Crystal Structure of MIL-91(Al).

ABSTRACT: The structure of one of the first permanently porous metal phosphonates, MIL-91(Al) was re-determined using high resolution synchrotron powder X-ray diffraction data. The new model is in a lower symmetry space group, with no disordered ligands in the structure, whilst remaining otherwise consistent with the reported compound. New milder synthetic conditions were also developed.

SUBMITTER: Hermer N

PROVIDER: S-EPMC5324569 | biostudies-literature | 2017 Jan

REPOSITORIES: biostudies-literature

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Re-Determination of the Crystal Structure of MIL-91(Al).

Hermer Nele N Wharmby Michael T MT Stock Norbert N

Zeitschrift fur anorganische und allgemeine Chemie 20161216 2

The structure of one of the first permanently porous metal phosphonates, MIL-91(Al) was re-determined using high resolution synchrotron powder X-ray diffraction data. The new model is in a lower symmetry space group, with no disordered ligands in the structure, whilst remaining otherwise consistent with the reported compound. New milder synthetic conditions were also developed. ...[more]

PMID: 28286349

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Synthesis and Properties of a Compositional Series of MIL-53(Al) Metal-Organic Framework Crystal-Glass Composites.

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Unraveling the molecular mechanism of MIL-53(Al) crystallization.

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