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Crystal structure of bis-(aceto-nitrile-?N)bis-(4-benzoyl-pyridine-?N)bis-(thio-cyanato-?N)cobalt(II).


ABSTRACT: The crystal structure of the title compound, [Co(NCS)2(C2H3N)2(C12H9NO)2], consists of cobalt(II) cations that are octa-hedrally coordinated by the N atoms of two terminal thio-cyanate anions, two aceto-nitrile mol-ecules and two 4-benzoyl-pyridine ligands. The discrete complexes are located on centres of inversion. They are connected by weak inter-molecular C-H?O and C-H?S hydrogen-bonding inter-actions between one of the pyridine H atoms and the carbonyl O atom, and between one of the methyl H atoms of the aceto-nitrile mol-ecule and the thio-cyanate S atoms into layers parallel to (101). No pronounced inter-molecular inter-actions are observed between these layers.

SUBMITTER: Suckert S 

PROVIDER: S-EPMC5347055 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature

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Crystal structure of bis-(aceto-nitrile-κ<i>N</i>)bis-(4-benzoyl-pyridine-κ<i>N</i>)bis-(thio-cyanato-κ<i>N</i>)cobalt(II).

Suckert Stefan S   Werner Julia J   Jess Inke I   Näther Christian C  

Acta crystallographica. Section E, Crystallographic communications 20170214 Pt 3


The crystal structure of the title compound, [Co(NCS)<sub>2</sub>(C<sub>2</sub>H<sub>3</sub>N)<sub>2</sub>(C<sub>12</sub>H<sub>9</sub>NO)<sub>2</sub>], consists of cobalt(II) cations that are octa-hedrally coordinated by the N atoms of two terminal thio-cyanate anions, two aceto-nitrile mol-ecules and two 4-benzoyl-pyridine ligands. The discrete complexes are located on centres of inversion. They are connected by weak inter-molecular C-H⋯O and C-H⋯S hydrogen-bonding inter-actions between one of  ...[more]

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