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Crystal structure of 4,10-dimeth-oxy-13-methyl-6H,12H-6,12-epimino-dibenzo[b,f][1,5]dioxocine.

ABSTRACT: The title compound, C₁₇H₁₇NO₄, lacks crystallographic symmetry with one mol-ecule per asymmetric unit. The mol-ecule exists in a folded butterfly-like conformation; the benzene rings form a dihedral angle of 84.72?(7)°. The central eight-membered imino-bridged dioxocin ring adopts a twisted-boat conformation. In the crystal, inversion-related mol-ecules are linked by pairs of weak C-H?O hydrogen bonds, forming double-stranded chains parallel to the a axis.

SUBMITTER: Kasyanova KV

PROVIDER: S-EPMC5347066 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature

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Crystal structure of 4,10-dimeth-oxy-13-methyl-6H,12H-6,12-epimino-dibenzo[b,f][1,5]dioxocine.

Kasyanova Katerina V KV Kokozay Vladimir N VN Buvaylo Elena A EA Vassilyeva Olga Yu OY Skelton Brian W BW

Acta crystallographica. Section E, Crystallographic communications 20170221 Pt 3

The title compound, C17H17NO4, lacks crystallographic symmetry with one mol-ecule per asymmetric unit. The mol-ecule exists in a folded butterfly-like conformation; the benzene rings form a dihedral angle of 84.72 (7)°. The central eight-membered imino-bridged dioxocin ring adopts a twisted-boat conformation. In the crystal, inversion-related mol-ecules are linked by pairs of weak C-H⋯O hydrogen bonds, forming double-stranded chains parallel to the a axis. ...[more]

PMID: 28316821

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