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Functional conductive nanomaterials via polymerisation in nano-channels: PEDOT in a MOF.


ABSTRACT: Reactions inside the pores of metal-organic frameworks (MOFs) offer potential for controlling polymer structures with regularity to sub-nanometre scales. We report a wet-chemistry route to poly-3,4-ethylenedioxythiophene (PEDOT)-MOF composites. After a two-step removal of the MOF template we obtain unique and stable macroscale structures of this conductive polymer with some nanoscale regularity.

SUBMITTER: Wang T 

PROVIDER: S-EPMC5361137 | biostudies-literature | 2017 Jan

REPOSITORIES: biostudies-literature

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Functional conductive nanomaterials <i>via</i> polymerisation in nano-channels: PEDOT in a MOF.

Wang Tiesheng T   Farajollahi Meisam M   Henke Sebastian S   Zhu Tongtong T   Bajpe Sneha R SR   Sun Shijing S   Barnard Jonathan S JS   Lee June Sang JS   Madden John D W JDW   Cheetham Anthony K AK   Smoukov Stoyan K SK  

Materials horizons 20160822 1


Reactions inside the pores of metal-organic frameworks (MOFs) offer potential for controlling polymer structures with regularity to sub-nanometre scales. We report a wet-chemistry route to poly-3,4-ethylenedioxythiophene (PEDOT)-MOF composites. After a two-step removal of the MOF template we obtain unique and stable macroscale structures of this conductive polymer with some nanoscale regularity. ...[more]

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