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High Curie temperature and enhanced magnetoelectric properties of the laminated Li_0.058(Na_0.535K_0.48)_0.942NbO₃/Co_0.6 Zn_0.4Fe_1.7Mn_0.3O₄ composites.

ABSTRACT: Laminated magnetoelectric composites of Li_0.058(Na_0.535K_0.48)_0.942NbO₃ (LKNN)/Co_0.6Zn_0.4Fe_1.7Mn_0.3O₄ (CZFM) prepared by the conventional solid-state sintering method were investigated for their dielectric, magnetic, and magnetoelectric properties. The microstructure of the laminated composites indicates that the LKNN phase and CZFM phase can coexist in the composites. Compared with the particulate magnetoelectric composites, the laminated composites have better piezoelectric and magnetoelectric properties due to their higher resistances and lower leakage currents. The magnetoelectric behaviors lie on the relative mass ratio of LKNN phase and CZFM phase. The laminated composites possess a high Curie temperature (T_C) of 463?°C, and the largest ME coefficient of 285?mV/cm Oe, which is the highest value for the lead-free bulk ceramic magnetoelectric composites so far.

SUBMITTER: Yang H

PROVIDER: S-EPMC5364461 | biostudies-literature | 2017 Mar

REPOSITORIES: biostudies-literature

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High Curie temperature and enhanced magnetoelectric properties of the laminated Li0.058(Na0.535K0.48)0.942NbO3/Co0.6 Zn0.4Fe1.7Mn0.3O4 composites.

Yang Haibo H Zhang Jintao J Lin Ying Y Wang Tong T

Scientific reports 20170324

Laminated magnetoelectric composites of Li0.058(Na0.535K0.48)0.942NbO3 (LKNN)/Co0.6Zn0.4Fe1.7Mn0.3O4 (CZFM) prepared by the conventional solid-state sintering method were investigated for their dielectric, magnetic, and magnetoelectric properties. The microstructure of the laminated composites indicates that the LKNN phase and CZFM phase can coexist in the composites. Compared with the p ...[more]

PMID: 28338006

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Project description:The further development of solid oxide fuel and electrolysis cells (SOFC/SOEC) strongly relies on research activities dealing with electrode materials. Recent studies showed that under operating conditions many perovskite-type oxide electrodes are prone to changes of their surface composition, leading to severe changes of their electrochemical performance. This results in a large scatter of data in literature and complicates comparison of materials. Moreover, little information is available on the potentially excellent properties of surfaces immediately after preparation, that is, before any degradation by exposure to other gas compositions or temperature changes. Here, we introduce in situ impedance spectroscopy during pulsed laser deposition (IPLD) as a new method for electrochemical analysis of mixed ionic and electronic conducting (MIEC) thin films during growth. First, this approach can truly reveal the properties of as-prepared MIEC electrode materials, since it avoids any alterations of their surface between preparation and investigation. Second, the measurements during growth give information on the thickness dependence of film properties. This technique is applied to La0.6Sr0.4CoO3-? (LSC), one of the most promising SOFC/SOEC oxygen electrode material. From the earliest stages of LSC film deposition on yttria-stabilized zirconia (YSZ) to a fully grown thin film of 100 nm thickness, data are gained on the oxygen exchange kinetics and the defect chemistry of LSC. A remarkable reproducibility is found in repeated film growth experiments, not only for the bulk related chemical capacitance but also for the surface related polarization resistance (±10%). Polarization resistances of as-prepared LSC films are extraordinarily low (2.0 ? cm2 in 40 ?bar O2 at 600 °C). LSC films on YSZ and on La0.95Sr0.05Ga0.95Mg0.05O3-? (LSGM) single crystals exhibit significantly different electrochemical properties, possibly associated with the tensile strain of LSC on LSGM.

Dataset Information

High Curie temperature and enhanced magnetoelectric properties of the laminated Li_0.058(Na_0.535K_0.48)_0.942NbO₃/Co_0.6 Zn_0.4Fe_1.7Mn_0.3O₄ composites.

Publications

High Curie temperature and enhanced magnetoelectric properties of the laminated Li<sub>0.058</sub>(Na<sub>0.535</sub>K<sub>0.48</sub>)<sub>0.942</sub>NbO<sub>3</sub>/Co<sub>0.6</sub> Zn<sub>0.4</sub>Fe<sub>1.7</sub>Mn<sub>0.3</sub>O<sub>4</sub> composites.

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