Ontology highlight
ABSTRACT:
SUBMITTER: Wang B
PROVIDER: S-EPMC5376677 | biostudies-literature | 2017 Mar
REPOSITORIES: biostudies-literature
Wang Bin B Lee Yong-Min YM Tcho Woon-Young WY Tussupbayev Samat S Kim Seoung-Tae ST Kim Yujeong Y Seo Mi Sook MS Cho Kyung-Bin KB Dede Yavuz Y Keegan Brenna C BC Ogura Takashi T Kim Sun Hee SH Ohta Takehiro T Baik Mu-Hyun MH Ray Kallol K Shearer Jason J Nam Wonwoo W
Nature communications 20170324
Terminal cobalt(IV)-oxo (Co<sup>IV</sup>-O) species have been implicated as key intermediates in various cobalt-mediated oxidation reactions. Herein we report the photocatalytic generation of a mononuclear non-haem [(13-TMC)Co<sup>IV</sup>(O)]<sup>2+</sup> (2) by irradiating [Co<sup>II</sup>(13-TMC)(CF<sub>3</sub>SO<sub>3</sub>)]<sup>+</sup> (1) in the presence of [Ru<sup>II</sup>(bpy)<sub>3</sub>]<sup>2+</sup>, Na<sub>2</sub>S<sub>2</sub>O<sub>8</sub>, and water as an oxygen source. The interme ...[more]