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ABSTRACT:
SUBMITTER: Pearce AJ
PROVIDER: S-EPMC5392362 | biostudies-literature | 2016 Oct
REPOSITORIES: biostudies-literature
Pearce Adam J AJ Cassabaum Alyssa A AA Gast Grace E GE Frontiera Renee R RR Tonks Ian A IA
Angewandte Chemie (International ed. in English) 20161001 42
The synthesis of the first terminal Group 9 hydrazido(2-) complex, Cp*IrN(TMP) (6) (TMP=2,2,6,6-tetramethylpiperidine) is reported. Electronic structure and X-ray diffraction analysis indicate that this complex contains an Ir-N triple bond, similar to Bergman's seminal Cp*Ir(N<sup>t</sup> Bu) imido complex. However, in sharp contrast to Bergman's imido, 6 displays remarkable redox non-innocent reactivity owing to the presence of the N<sub>β</sub> lone pair. Treatment of 6 with MeI results in ele ...[more]