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Sodium-Ion Batteries: Improving the Rate Capability of 3D Interconnected Carbon Nanofibers Thin Film by Boron, Nitrogen Dual-Doping.

ABSTRACT: Boron, nitrogen dual-doping 3D hard carbon nanofibers thin film is synthesized using a facile process. The nanofibers exhibit high specific capacity and remarkable high-rate capability due to the synergistic effect of 3D porous structure, large surface area, and enlarged carbon layer spacing, and the B, N codoping-induced defects.

SUBMITTER: Wang M

PROVIDER: S-EPMC5396155 | biostudies-literature | 2017 Apr

REPOSITORIES: biostudies-literature

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Sodium-Ion Batteries: Improving the Rate Capability of 3D Interconnected Carbon Nanofibers Thin Film by Boron, Nitrogen Dual-Doping.

Wang Min M Yang Yang Y Yang Zhenzhong Z Gu Lin L Chen Qianwang Q Yu Yan Y

Advanced science (Weinheim, Baden-Wurttemberg, Germany) 20170120 4

<b>Boron, nitrogen dual-doping 3D hard carbon nanofibers thin film</b> is synthesized using a facile process. The nanofibers exhibit high specific capacity and remarkable high-rate capability due to the synergistic effect of 3D porous structure, large surface area, and enlarged carbon layer spacing, and the B, N codoping-induced defects. ...[more]

PMID: 28435779

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Project description:Currently, the limited availability of lithium sources is escalating the cost of lithium-ion batteries (LIBs). Considering the fluctuating economics of LIBs, sodium-ion batteries (SIBs) have now drawn attention because sodium is an earth-abundant, low-cost element that exhibits similar chemistry to that of LIBs. Despite developments in different anode materials, there still remain several challenges in SIBs, including lighter cell design for SIBs. The presented work designs a facile strategy to prepare nitrogen-doped free-standing pseudo-graphitic nanofibers via electrospinning. A structural and morphological study implies highly disordered graphitic structured nanofibers having diameters of ∼120-170 nm, with a smooth surface. X-ray photoelectron spectroscopy analysis showed that nitrogen was successfully doped in carbon nanofibers (CNFs). When served as an anode material for SIBs, the resultant material exhibits excellent sodium-ion storage properties in terms of long-term cycling stability and high rate capability. Notably, a binder-free self-standing CNF without a current collector was used as an anode for SIBs that delivered capacities of 210 and 87 mA h g-1 at 20 and 1600 mA g-1, respectively, retaining a capacity of 177 mA h g-1 when retained at 20 mA g-1. The as-synthesized CNFs demonstrate a long cycle life with a relatively high Columbic efficiency of 98.6% for the 900th cycle, with a stable and excellent rate capacity. The sodium storage mechanisms of the CNFs were examined with various nitrogen concentrations and carbonization temperatures. Furthermore, the diffusion coefficients of the sodium ions based on the electrochemical impedance spectra measurement have been calculated in the range of 10-15-10-12 cm2 s-1, revealing excellent diffusion mobility for Na atoms in the CNFs. This study demonstrates that optimum nitrogen doping and carbonization temperature demonstrated a lower Warburg coefficient and a higher Na-ion diffusion coefficient leads to enhanced stable electrochemical performance. Thus, our study shows that the nitrogen-doped CNFs will have potential for SIBs.

Dataset Information

Sodium-Ion Batteries: Improving the Rate Capability of 3D Interconnected Carbon Nanofibers Thin Film by Boron, Nitrogen Dual-Doping.

Publications

Sodium-Ion Batteries: Improving the Rate Capability of 3D Interconnected Carbon Nanofibers Thin Film by Boron, Nitrogen Dual-Doping.

Similar Datasets

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