Radicals from the gas-phase pyrolysis of a lignin model compound: p-coumaryl alcohol.
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ABSTRACT:
SUBMITTER: Xu MX
PROVIDER: S-EPMC5407301 | biostudies-literature | 2016
REPOSITORIES: biostudies-literature
Publications
Radicals from the gas-phase pyrolysis of a lignin model compound: <i>p</i>-coumaryl alcohol.
Xu Meng-Xia MX Khachatryan Lavrent L Baev Alexander A Asatryan Rubik R
RSC advances 20160615 67
The intermediate radicals produced in the gas-phase pyrolysis of one of the main building blocks of lignin - <i>p</i>-coumaryl alcohol (<i>p</i>-CMA) - were investigated using the low temperature matrix isolation technique interfaced with electron paramagnetic resonance spectroscopy (LTMI-EPR). An anisotropic EPR spectrum characterized by a high <i>g</i>-value (>2.0080) and a relatively low saturation coefficient (∼1.40) throughout the high pyrolytic temperature region (700 to 1000 °C) was obser ...[more]
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