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Coulomb engineering of the bandgap and excitons in two-dimensional materials.

ABSTRACT: The ability to control the size of the electronic bandgap is an integral part of solid-state technology. Atomically thin two-dimensional crystals offer a new approach for tuning the energies of the electronic states based on the unusual strength of the Coulomb interaction in these materials and its environmental sensitivity. Here, we show that by engineering the surrounding dielectric environment, one can tune the electronic bandgap and the exciton binding energy in monolayers of WS₂ and WSe₂ by hundreds of meV. We exploit this behaviour to present an in-plane dielectric heterostructure with a spatially dependent bandgap, as an initial step towards the creation of diverse lateral junctions with nanoscale resolution.

SUBMITTER: Raja A

PROVIDER: S-EPMC5418602 | biostudies-literature | 2017 May

REPOSITORIES: biostudies-literature

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Coulomb engineering of the bandgap and excitons in two-dimensional materials.

Raja Archana A Chaves Andrey A Yu Jaeeun J Arefe Ghidewon G Hill Heather M HM Rigosi Albert F AF Berkelbach Timothy C TC Nagler Philipp P Schüller Christian C Korn Tobias T Nuckolls Colin C Hone James J Brus Louis E LE Heinz Tony F TF Reichman David R DR Chernikov Alexey A

Nature communications 20170504

The ability to control the size of the electronic bandgap is an integral part of solid-state technology. Atomically thin two-dimensional crystals offer a new approach for tuning the energies of the electronic states based on the unusual strength of the Coulomb interaction in these materials and its environmental sensitivity. Here, we show that by engineering the surrounding dielectric environment, one can tune the electronic bandgap and the exciton binding energy in monolayers of WS<sub>2</sub> ...[more]

PMID: 28469178

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