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Crystal structure of 10-ethyl-7-(9-ethyl-9H-carbazol-3-yl)-10H-pheno-thia-zine-3-carbaldehyde.


ABSTRACT: The title compound, C29H24N2OS, contains a pheno-thia-zine moiety linked to a planar carbazole unit (r.m.s. deviation = 0.029?Å) by a C-C single bond. The pheno-thia-zine moiety possesses a typical non-planar butterfly structure with a fold angle of 27.36?(9)° between the two benzene rings. The dihedral angle between the mean planes of the carbazole and pheno-thia-zine units is 27.28?(5)°. In the crystal, mol-ecules stack in pairs along the c-axis direction, linked by offset ?-? inter-actions [inter-centroid distance = 3.797?(1)?Å]. There are C-H?? inter-actions present linking these dimers to form a three-dimensional structure.

SUBMITTER: Mahalakshmi V 

PROVIDER: S-EPMC5418793 | biostudies-literature | 2017 May

REPOSITORIES: biostudies-literature

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Crystal structure of 10-ethyl-7-(9-ethyl-9<i>H</i>-carbazol-3-yl)-10<i>H</i>-pheno-thia-zine-3-carbaldehyde.

Mahalakshmi Vairavan V   Gouthaman Siddan S   Sugunalakshmi Madurai M   Bargavi Srinivasan S   Lakshmi Srinivasakannan S  

Acta crystallographica. Section E, Crystallographic communications 20170421 Pt 5


The title compound, C<sub>29</sub>H<sub>24</sub>N<sub>2</sub>OS, contains a pheno-thia-zine moiety linked to a planar carbazole unit (r.m.s. deviation = 0.029 Å) by a C-C single bond. The pheno-thia-zine moiety possesses a typical non-planar butterfly structure with a fold angle of 27.36 (9)° between the two benzene rings. The dihedral angle between the mean planes of the carbazole and pheno-thia-zine units is 27.28 (5)°. In the crystal, mol-ecules stack in pairs along the <i>c</i>-axis directio  ...[more]

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