Ontology highlight
ABSTRACT:
SUBMITTER: Benz M
PROVIDER: S-EPMC5424581 | biostudies-literature | 2015 Jan
REPOSITORIES: biostudies-literature
Benz Michael M Braband Henrik H Schmutz Paul P Halter Jonathan J Alberto Roger R
Chemical science 20140905 1
Bis-arene complexes of technetium represent a fundamental class of organometallic compounds. Due to complex synthetic routes, no detailed insights into their properties have been reported so far. Reacting [<sup>99</sup>TcO<sub>4</sub>]<sup>-</sup> with arenes in the exclusive presence of AlCl<sub>3</sub> gives highly stable [<sup>99</sup>Tc(arene)<sub>2</sub>]<sup>+</sup> in good yields. These complexes have extraordinarily high stabilities, where oxidation is found to occur at potentials higher ...[more]